A first approach to the characterization of water and sediments during the restoration of coal waste dumps in El Bierzo (NW Iberia)

Authors

  • Sara Alcalde Aparicio Department of Agricultural Sciences and Engineering, School of Agriculture Engineering, University or León https://orcid.org/0000-0002-9184-5214
  • Inés Pereira Rodríguez Department of Geography and Geology, Faculty of Biology and Environmental Sciences, University of León https://orcid.org/0000-0002-7328-4791
  • Juncal Altagracia Cruz Martínez Department of Geography and Geology, Faculty of Biology and Environmental Sciences, University of León https://orcid.org/0000-0003-2768-9242
  • Indira Rodríguez Álvarez Department of Geography and Geology, Faculty of Biology and Environmental Sciences, University of León
  • Marta Barrio Contreras Department of Agricultural Sciences and Engineering, School of Agriculture Engineering, University or León
  • Florin Faur Department of Environmental Engineering and Geology, University of Petrosani, Romania https://orcid.org/0000-0002-0880-0913
  • Montserrat Ferrer Julià Department of Geography and Geology, Faculty of Biology and Environmental Sciences, University of León https://orcid.org/0000-0001-8021-1040

DOI:

https://doi.org/10.55407/geogaceta113534

Keywords:

mineralogy, restoration works, tailing, diffuse reflectance spectroscopy, environmental impacts

Abstract

Coal mining has been related to the problems of acid mine drainage (AMD) or acid rock drainage (ARD), causing high acidity and contamination by metals. Coal mining in El Bierzo coal basin, NW Iberian Peninsula, has resulted in several abandoned tailings from past mining that still affect water chemistry and sediment composition. Recent restoration actions, including the expansion of roads, have introduced fresh waste materials and accelerated the oxidative weathering and sediment transport into La Silva river. Water analyses continue to show low pH (~4.5) and high sulfate concentrations supporting sulfide oxidation. The VNIR-SWIR diffuse reflectance spectroscopy initially identified iron oxides such as goethite in the sediments, and later illite, a product of erosion and deposition of waste materials. This indicates that the runoff generated after the rainfall episodes has transported sediments of different mineral composition by mobilizing material from the waste dumps. The study highlights the importance of continuous monitoring to assess the evolving geochemical conditions and potential secondary alterations in the river system. Reflectance spectroscopy has proved to be a useful technique for rapid mineral identification, distinguishing oxidation effects from erosion impacts, making it a valuable tool for environmental assessments.

References

Alcalde-Aparicio, S., Vidal-Bardan, M. and Alonso-Herrero, E. (2022) Earth Sciences Research Journal 26 (1), 55-68. https://doi.org/10.15446/esrj.v26n1.81087

Bigham, J.M., Schwertmann, U., Carlson, L. and Murad, E. (1990). Geochimica Cosmochimica Acta 54, 2743-2754. https://doi.org/10.1016/0016-7037(90)90009-A

Crowley, J.K., Williams, D.E., Hammarstrom, J. M., Piatak, N.M.C.I., Chou, I.M., and Mars, J.C. (2003). Geochemistry: Exploration, Environment, Analysis, 3 (3), 219-228. https://doi.org/10.1144/1467-7873/03-001

Heredia, N., Rodríguez Fernández, L.R. and Suárez, A. (1994). In: Rodríguez Fernández, L.R. and Heredia, N. (Coords.). Memoria del Mapa Geológico de la provincia de León a escala 1:200.000. Instituto Tecnológico Geominero de España (ITGE). Ministerio de Industria y Energía. Diputación de León, Madrid. 166 pp.

Hunt, G.R. (1977). Geophysics 42(3), 501- 513. https://doi.org/10.1190/1.1440721

Jönsson, J., Jönsson, J. and Lövgren, L. (2006). Applied Geochemistry 21, 437-445. https://doi.org/10.1016/j.apgeochem.2005.12.008

Nordstrom, D.K. (1982). In: Kitrick, J.A., Fanning, D.S. and Hossner, L.R. (Eds.). Acid sulfate weathering. Soil Science Society of America, Madison, WI, 37-56.

Nordstrom, D.K. and Alpers, C.N. (1999). Environmental Geochemistry of Mineral Deposits, Economy Geology 6A, 133-160. https://doi.org/10.5382/Rev.06.06

Ribeiro, J., Suarez-Ruiz, I., Ward, C. R., and Flores, D. (2016). Journal of coal geology, 154, 92-106. https://doi.org/10.1016/j.coal.2015.12.011

Rodríguez Gómez, V., Vadillo Fernández, L., Lacal Guzmán, M., Alberruche E., Herrero Barrero, T. and De la Losa Román, A. (2010). Boletín Geológico y Minero 121 (1), 89-102.

Santamaría-López, Á. and Suárez, M. (2024). Minerals 14, 1098. https://doi.org/10.3390/min14111098

Santofimia, E and López Pamo, E. (2016). Environ. Sci. Pollut. Res. 23, 14502-14517. https://doi.org/10.1007/s11356-016-6562-z

Shum, M. and lavkulich, l. (1999). Environmental Geology 38 (1), 59-68. https://doi.org/10.1007/s002540050401

Villa Bermejo, E., Alcalde Aparicio, S., Alonso Herrero, E. and Vidal Bardán, M. (2008). Sociedad Española de Mineralogía. Macla 10, 147 148.

Downloads

Published

2025-12-11

How to Cite

Alcalde Aparicio, S., Pereira Rodríguez, I., Cruz Martínez, J. A., Rodríguez Álvarez, I., Barrio Contreras, M., Faur, F., & Ferrer Julià, M. (2025). A first approach to the characterization of water and sediments during the restoration of coal waste dumps in El Bierzo (NW Iberia). GEOGACETA, 78, 67–70. https://doi.org/10.55407/geogaceta113534

Issue

Section

Artículos

Most read articles by the same author(s)