INFLUENTIAL FACTORS ON THE OXIDATION STABILITY OF BIODIESEL: STATISTICAL STUDY.

Authors

  • JAVIER TARRIO SAAVEDRA Universidad de la Coruña
  • JORGE LOPEZ BECEIRO Universidad de La Coruña
  • SALVADOR NAYA FERNANDEZ Universidad de la Coruña
  • JOSÉ L. MIER BUENHOMBRE Universidad de la Coruña
  • RAMON ARTIAGA DIAZ Universidad de la Coruña
  • CARLOS GRACIA FERNANDEZ Ta Instr

Keywords:

biodiesel, estabilidad a la oxidación, OOT, diseño de experimentos, PDSC.

Abstract

In this study the effect of the level of oxygen pressure, the concentration of antioxidant and the type of biodiesel on the oxidative stability of the material have been measured. An experimental design was performed considering two types of biodiesel, various pressures of oxygen and additions of a commercial antioxidant. As a response variable was chosen Oxidation Onset Temperature (OOT), measured by Pressure Differential Scanning Calorimetry (PDSC). It has been found that the design that best fits the data is the replicated main effects model with three treatment factors. The sequence of factors, sorted in descending order according to their influence in the OOT resulted to be: Pressure > Type of biodiesel > Antioxidant. It has been also observed an interaction by mixing 50% by weight of the two types of biodiesel, which produces some deviation from the expected linear behaviour.

Published

2010-04-29

Issue

Section

ARTICULOS